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Title: GEOCHEMICAL METHOD FOR IDENTIFYING ALKALI-SILICA-REACTION GEL
Accession Number: 00771114
Record Type: Component
Record URL: Availability: Transportation Research Board Business Office 500 Fifth Street, NW Find a library where document is available Abstract: A geochemical method for staining various products of the alkali-silica reaction is presented. The method is based on both the composition of alkali-silica-reaction (ASR) gel and one of its properties (the ability to exchange cations with a fluid). Specifically, one stain (sodium cobalt nitrite) reacts with exchangeable potassium in the gel to form a bright yellow precipitate on the gel surface. The other class of stains (a variety of rhodamine compounds) reacts with calcium-rich portions of the gel (and, for some compounds, with other calcium-rich components of the concrete) to form a pink-stained gel. The significance of the pink staining is twofold. First, it can provide a high contrast to the yellow-stained gels, making them easier to observe. Second, some rhodamine compounds react predominantly with calcium-rich ASR gels. Some aspects of staining by rhodamine remain the subject of continued study and may be useful for a more detailed understanding of ASR progression and other deterioration mechanisms. However, a positive diagnosis of ASR is indicated by the presence of yellow-stained gel within aggregate, at the aggregate-paste interface, along fractures, or in air voids. The technique can be used as a rapid field screening method or as a useful aid for detailed petrographic examinations.
Supplemental Notes: This paper appears in Transportation Research Record No. 1668, Concrete in Pavements and Structures.
Language: English
Corporate Authors: Transportation Research Board 500 Fifth Street, NW Authors: Guthrie Jr, G DCarey, J WPagination: p. 68-71
Publication Date: 1999
Serial: ISBN: 0309070635
Features: Figures
(1)
; References
(7)
TRT Terms: Uncontrolled Terms: Subject Areas: Highways; Materials; I32: Concrete
Files: TRIS, TRB, ATRI
Created Date: Oct 7 1999 12:00AM
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