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Title:

Factors Affecting Oxidation Reaction Mechanisms in Asphalt Concrete

Accession Number:

01629821

Record Type:

Component

Abstract:

The accurate characterization and prediction of asphalt mixture properties with regard to pavement service life are becoming more important as increasingly powerful pavement design and performance prediction methods are being implemented. Oxidative aging, as a major distress mechanism of asphalt concrete pavements, causes the asphalt concrete to stiffen and embrittle, which leads to a high potential for cracking in pavements. Thus, an improved understanding of the factors that affect oxidation reactions will inform improved laboratory aging procedures and predictive oxidation models. An experimental plan that includes laboratory binder aging, laboratory mixture aging, and field-aged materials was implemented in this study to elucidate the factors that affect oxidation mechanisms in asphalt concrete. The relationships between rheological and chemical aging index properties were used to detect differences in the oxidation mechanisms. The results demonstrate that oxidative aging at temperatures over 100°C can alter the oxidation mechanisms and should be avoided in long-term laboratory aging. The results also demonstrate that aging mixtures in a compacted versus loose mixture state can determine whether the oxidation reaction is diffusion- or kinetics-controlled. The application of pressure and the aggregate interactions with the binder may also impact the oxidation reaction, suggesting that standard binder aging methods cannot fully reflect mixture aging. A comparison between binders extracted from laboratory-aged loose mixtures and from field cores suggests that field aging is diffusion-controlled underneath the pavement surface. In addition, oxidation at the pavement surface differs from oxidation in laboratory-aged loose mixtures even though both pavement surface and loose mixtures are speculated to experience kinetics-driven oxidation, suggesting that ultraviolet photo-oxidation and/or other field variables may affect pavement oxidation, which cannot be easily replicated in the laboratory.

Supplemental Notes:

This paper was sponsored by TRB committee AFK20 Standing Committee on Asphalt Binders.

Monograph Accession #:

01618707

Report/Paper Numbers:

17-05969

Language:

English

Corporate Authors:

Transportation Research Board

500 Fifth Street, NW
Washington, DC 20001 United States

Authors:

Elwardany, Michael D
Rad, Farhad Yousefi
Castorena, Cassie
Kim, Y Richard

Pagination:

20p

Publication Date:

2017

Conference:

Transportation Research Board 96th Annual Meeting

Location: Washington DC, United States
Date: 2017-1-8 to 2017-1-12
Sponsors: Transportation Research Board

Media Type:

Digital/other

Features:

Figures; References; Tables

Uncontrolled Terms:

Subject Areas:

Highways; Materials; Pavements

Source Data:

Transportation Research Board Annual Meeting 2017 Paper #17-05969

Files:

TRIS, TRB, ATRI

Created Date:

Dec 8 2016 12:24PM